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Table 4 Merits and demerits of diverse approaches used to fabricate functional NW -based EMI shields

From: Progress in polymer nonwoven textile materials in electromagnetic interference shielding applications

Approach

Merit(s)

Demerit(s)

Ref

Dip-coating

Approach is cheap

Several coating layers can be administered

It is feasible to prepare many layers of various materials simultaneously

Film surface quality is directly influenced by the annealing temperature, precursor content, as well as any additives or solvents utilized

Control of coating thickness is challenging

[9]

Melt extrusion/compounding

Suitable for processing polymeric composite materials

Solvent free

Scalable

No need for processing downstream

High outlook

Broad application in advanced materials

Limited exposure to oxygen within the extrusion channel

It is a continuous process

Not suitable for metal–metal composite systems

Degradation of some functional reinforcing fillers may occur during processing

Raw materials with high flow characteristics are needed

Energy consuming

[9]

Electroless deposition

There are no issues with the current network

Insulators like glass, ceramics, and polymers could be covered with nanosheets of metals, alloys, as well as compounds

It is just a basic deposition tool

Compared to other vacuum deposition techniques, this method has a low temperature

It is not necessary to create a vacuum environment

produces homogeneous, high-quality films

cheaper than the standard vacuum deposition, spray pyrolysis technique

The least amount of energy is required to produce one unit area of chemically deposited materials, such as CdS film deposition

Byproducts may react as the solution ages, altering the fabrication

Owing to contamination or other issues, nontargeted nucleation and failure to nucleate or develop films on specific regions solely with the catalyst surface

The process is time-consuming

The rate of deposition is not very high

obtaining a film thickness greater than 1 m in a single-dip deposition is difficult

[9]

Electrospinning

Works well with polymeric composite systems

Excellent approach to fabricate nanofibrous non-woven mats

Scalable approach

Inexpensive process

Bicomponent fibers can be produced using this approach

Not very suitable for metal–metal composites

It is expensive for scaled production

Needle clogging is a great challenge

Low feed rate and production rate

Control of fiber size and morphology can be challenging

Challenging to process immiscible polymer blends

 

3D printing

Works well with polymeric composite systems

Excellent approach to fabricate microfibrous non-woven mats

Scalable

Not very suitable for metal–metal composites

It is expensive for scaled production

Not suitable for NF production

 

Spray coating/deposition

It is simple to obtain a film that covers a sizable area

It can be easily scaled

Spray pyrolysis is a less costly alternative to the conventional vacuum deposition technique

Solvent recovery is a challenge

Often made to include fibers and whiskers; therefore, the alternatives for matrix alloys are restricted

[9]

Vacuum-assisted filtration-based deposition

Simple to use

Require too much time

It can be only used to fabricate films of limited thickness and area

Its scalability is limited

The mechanical properties of the deposit and their influence by control parameters on residual stress molded thin films as well as highly porous membranes are also little understood

It is unclear how the energy of the depositing species affects interfacial contact, nucleation, and deposit formation

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